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51.
Bünyamin Ak Duygu Elma Nermin Meriç Cezmi Kayan Uğur Işık Murat Aydemir Feyyaz Durap Akın Baysal 《Tetrahedron: Asymmetry》2013,24(20):1257-1264
A new and versatile class of unsymmetrical ferrocenyl-phosphinite ligands possessing a stereogenic center has been prepared from commercially available, inexpensive aminoacids such as, d-, l-phenylglycine and d-, l-phenylalanine, through a concise synthetic procedure. These ligands are not very sensitive to air and moisture, and display good enantioselectivities in the ruthenium-catalyzed asymmetric transfer hydrogenation of acetophenone derivatives, in which up to 91% ee was obtained. A comparison of the catalytic properties of amino alcohols and other analogues based on a ferrocenyl backbone is also discussed briefly. The structures of these ligands and their corresponding complexes have been elucidated by a combination of multinuclear NMR spectroscopy, IR spectroscopy, and elemental analysis. 相似文献
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The numerical investigation of wave propagation in the asymptotic domain of Kerr spacetime has only recently been possible thanks to the construction of suitable hyperboloidal coordinates. The asymptotics revealed an apparent puzzle in the decay rates of scalar fields: the late-time rates seemed to depend on whether finite distance observers are in the strong field domain or far away from the rotating black hole, an apparent phenomenon dubbed ‘splitting.’ We discuss far-field ‘splitting’ in the full field and near-horizon ‘splitting’ in certain projected modes using horizon-penetrating, hyperboloidal coordinates. For either case we propose an explanation to the cause of the ‘splitting’ behavior, and we determine uniquely decay rates that previous studies found to be ambiguous or immeasurable. The far-field ‘splitting’ is explained by competition between projected modes. The near-horizon ‘splitting’ is due to excitation of lower multipole modes that back excite the multipole mode for which ‘splitting’ is observed. In both cases ‘splitting’ is an intermediate effect, such that asymptotically in time strong field rates are valid at all finite distances. At any finite time, however, there are three domains with different decay rates whose boundaries move outwards during evolution. We then propose a formula for the decay rate of tails that takes into account the inter-mode excitation effect that we study. 相似文献
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Algebras and Representation Theory - Let A be an abelian group such that torn(A) is finite for every n ≥?1 and let ${\mathbb{K}}$ be a field of characteristic zero containing roots of... 相似文献
56.
Güveli Şükriye Özdemir Namık Bal-Demirci Tülay Soylu Mustafa Serkan Ülküseven Bahri 《Transition Metal Chemistry》2019,44(2):115-123
Transition Metal Chemistry - Mixed ligand Ni(II) complexes were synthesized from triphenylphosphine and S-methyl- or S-ethyl-isothiosemicarbazone ligands derived from... 相似文献
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The Ramanujan Journal - Answering a question of Erdös, Komlós proved in 1968 that almost all $$n\times n$$ Bernoulli matrices are nonsingular as $$n\rightarrow \infty $$ . In this paper,... 相似文献
58.
Fırıncı Rukiye Fırıncı Erkan Başbülbül Gamze Dabanca Mustafa Berk Barut Celepci Duygu Günay M. Emin 《Transition Metal Chemistry》2019,44(4):391-397
Transition Metal Chemistry - Three 1,3-dimethylbarbiturate-enamine derivatives and their symmetrical palladium(II) complexes were prepared and characterized by spectroscopic methods. In addition,... 相似文献
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Positivity - Many researchers have been interested in the concept of statistical convergence because of the fact that it is stronger than the classical convergence. Also, the concepts of... 相似文献
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ABSTRACT In this paper, the radiation shielding parameters such as linear attenuation coefficients (LAC, µ), mass attenuation coefficients (MAC, µ/ρ), effective atomic numbers (Zeff), effective electron densities (Neff), half value of layers (HVL), mean free paths (MFP) and buildup factors (exposure (EBF) and energy absorption (EABF)) were investigated for cream (M1), pink (M2), white (M3), maroon (M4) and green (M5) marbles. Attenuation coefficients were measured in the energy region 31.18–661.66 keV photon energies. The values of Zeff and Neff were then calculated using these coefficients with logarithmic interpolation method, and HVLs and MFPs were calculated using the values of LAC of marble samples at the same photon energies. The experimental results were compared with the theoretical values obtained from WinXCom program, and good agreements were observed between the experimental and theoretical results. HVLs and MFPs of all marble samples were compared with those of some concretes, glasses and commercial radiation shielding glasses (SCHOTT Co.). The studied marbles were better radiation shielding materials than standard shielding concretes due to lower HVL and MFP values lower than the ordinary concrete. Finally, EBFs and EABFs of the marbles were calculated in the energy region 0.015–1?MeV up to penetration depths of 40 mfps by Geometric Progression method (G-P), and the results were discussed in terms of photon energies and chemical compositions of the marbles. 相似文献